| 1. Sandra Myers |  Spain | 23.15s | | | 2. Erika Suchovská |  Czechia | 23.16s | PB | | 3. Zlatka Georgieva |  Bulgaria | 23.40s | | | 4. Alenka Bikar |  Slovenia | 23.68s | | | 1. Marina Zhirova |  Russia | 23.72s | | | 2. Christine Arron |  France | 23.74s | | | 3. Fabé Dia | France | 24.04s | | | 4. Maya Azarashvili |  Georgia | 24.06s | |
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| | First - from each Semi advanced to Final. |
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| | | First - from each Heat and next Best 4 advanced to Semi-Finals. |
| 1. Erika Suchovská | Czechia | 23.26s | Q | | 2. Nora Ivanova | Bulgaria | 23.43s | q | | 12.Marina Vasarmidou |  Greece | 24.31s | | | 1. Sandra Myers | Spain | 23.21s | Q | | 5. Fabé Dia | France | 23.73s | qB | | 6. Marina Zhirova | Russia | 23.81s | qB | | -. Nora Ivanova | Bulgaria | DQ | |
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| 7. Christine Arron | France | 23.88s | Q | | 9. Marina Zhirova | Russia | 24.00s | q | | -. Ŷznur Dursun |  Turkey | DNS | [2] | | 4. Zlatka Georgieva | Bulgaria | 23.58s | Q | | 7. Christine Arron | France | 23.89s | qB | | 8. Maya Azarashvili | Georgia | 24.12s | qB | | 10.Agnė Visockaitė |  Lithuania | 24.17s | |
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| 13.Monika Gachevska | Bulgaria | 24.40s | Q | | 16.Virna De Angeli |  Italy | 26.49s | | | -. Katerina Koffa | Greece | DQ | | | 2. Erika Suchovská | Czechia | 23.39s | Q | | 3. Alenka Bikar | Slovenia | 23.54s | q | | 9. Mireille Donders |  Switzerland | 24.13s | | | 11.Monika Gachevska | Bulgaria | 24.22s | |
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| 3. Zlatka Georgieva | Bulgaria | 23.68s | Q | | 10.Agnė Visockaitė | Lithuania | 24.04s | q | | 12.Mercedes Martín | Spain | 24.31s | |
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