date | Pair 1 | sets | Pair 2 | set 1 | set 2 | set 3 |
| Oksana Kalashnikova / Olga Savchuk | GEO | UKR | 1 | bye |
--- --.07.14 | N Abduraimova / Alona Fomina | UZB | UKR | | 2-1 | M Eguchi / P Mayr-Achleitner | JPN | AUT | | 6-2 | 4-6 | 10-5 |
--- --.07.14 | Kateryna Bondarenko / Nicole Melichar | UKR | USA | | 2-0 | J Glushko / S Klemenschits | ISR | AUT | 4 | 6-4 | 6-0 | |
--- --.07.14 | A Panova / Heather Watson | RUS | GBR | | 2-1 | B Jovanovski / D Kovinic | SRB | MNE | | 6-4 | 5-7 | 11-9 |
--- --.07.14 | A Hesse / Pauline Parmentier | FRA | FRA | | 2-1 | A Sasnovich / Katerina Siniakova | BLR | CZE | | 6-2 | 2-6 | 12-10 |
--- --.07.14 | Raluca Olaru / S Peer | ROU | ISR | 3 | 2-1 | A Cadantu / Katarzyna Piter | ROU | POL | | 3-6 | 6-3 | 10-4 |
--- --.07.14 | O Korashvili / T Martincova | UKR | CZE | WC | 2-0 | T Chalaganidze / N Jafarova | GEO | AZE | WC | 6-0 | 6-0 | |
--- --.07.14 | Francesca Schiavone / Stefanie Voegele | ITA | SUI | | 2-1 | J Husarova / K Jans-Ignacik | SVK | POL | 2 | 3-6 | 6-4 | 10-2 |