date | Pair 1 | sets | Pair 2 | set 1 | set 2 | set 3 |
| Cornelia Lister / Renata Voracova | SWE | CZE | 1 | bye |
Mon 29.07.19 | Lara Arruabarrena / P Badosa Gibert | ESP | ESP | | 2-0 | J Paolini / Sara Sorribes Tormo | ITA | ESP | | 6-4 | 6-2 | |
Mon 29.07.19 | Daria Gavrilova / Shuai Peng | --- | CHN | 3 | 2-1 | E Bogdan / C Dinu | ROU | ROU | | 6-73 | 6-4 | 10-8 |
Mon 29.07.19 | E Elisabetta / F Federica | --- | | WC | 0-0 | M Di Giuseppe / G Gatto-Monticone | ITA | ITA | | | | |
Mon 29.07.19 | Alison Bai / Nicola Geuer | AUS | GER | | 2-1 | G Ce / P Goncalves | BRA | BRA | | 6-2 | 3-6 | 10-4 |
Mon 29.07.19 | A Grymalska / R Van Der Hoek | ITA | NED | | 2-0 | Giorgia Marchetti / Laura Pigossi | ITA | BRA | 4 | 6-4 | 7-5 | |
Mon 29.07.19 | Ekaterina Gorgodze / Arantxa Rus | GEO | NED | | 2-0 | Prathana Thombare / Eva Wacanno | IND | NED | | 7-62 | 7-64 | |
Mon 29.07.19 | F Bilardo / D Spiteri | ITA | ITA | WC | 2-1 | Georgina Garcia-Perez / Fanny Stollar | ESP | HUN | 2 | 7-5 | 2-6 | 10-8 |