| date | Pair 1 | sets | Pair 2 | set 1 | set 2 | set 3 | dur (points) |
| Sun 06.09.20 | Gabriela Dabrowski / Alison Riske |  CAN |  USA | | w/o | Timea Babos / Kristina Mladenovic |  HUN |  FRA | 1 | walk over |
| Fri 04.09.20 | Asia Muhammad / Taylor Townsend | USA | USA | | 2-1 | Lucie Hradecka / Andrea Klepac |  CZE |  SLO | | 6-3 | 6-76 | 6-0 | 2:07 (104-84) |
| Fri 04.09.20 | Nicole Melichar / Yifan Xu | USA |  CHN | 3 | 2-0 | Cori Gauff / Caty Mcnally | USA | USA | | 7-64 | 7-62 | | 1:44 (89-79) |
| Sat 05.09.20 | Hayley Carter / Luisa Stefani | USA |  BRA | | 2-1 | Shuko Aoyama / Ena Shibahara |  JPN | USA | 6 | 6-4 | 0-6 | 6-4 | 2:02 (88-98) |
| Fri 04.09.20 | Anna Blinkova / Veronika Kudermetova |  RUS | RUS | | 2-1 | Anna-Lena Friedsam / Katerina Siniakova |  GER | CZE | 8 | 6-3 | 3-6 | 6-1 | 1:39 (82-68) |
| Sat 05.09.20 | Kveta Peschke / Demi Schuurs | CZE |  NED | 4 | 2-0 | Oksana Kalashnikova / Alla Kudryavtseva |  GEO | RUS | | 6-2 | 7-5 | | 1:18 (71-60) |
| Fri 04.09.20 | Laura Siegemund / Vera Zvonareva | GER | RUS | | 2-0 | Victoria Azarenka / Sofia Kenin |  BLR | USA | 7 | 7-64 | 6-3 | | 1:31 (80-66) |
| Sat 05.09.20 | Elise Mertens / Aryna Sabalenka |  BEL | BLR | 2 | 2-0 | Jessica Pegula / Shelby Rogers | USA | USA | WC | 6-3 | 7-65 | | 1:26 (76-66) |
| date | Pair 1 | sets | Pair 2 | set 1 | set 2 | set 3 | dur (points) |
| Thu 03.09.20 | Timea Babos / Kristina Mladenovic | HUN | FRA | 1 | 2-0 | Kaitlyn Christian / Giuliana Olmos | USA |  MEX | | 6-2 | 6-2 | | 0:59 (63-44) |
| Thu 03.09.20 | Gabriela Dabrowski / Alison Riske | CAN | USA | | 2-0 | Nina Dzalamidze / Irina Khromacheva | RUS | RUS | | 6-3 | 6-2 | | 1:09 (74-56) |
| Wed 02.09.20 | Lucie Hradecka / Andrea Klepac | CZE | SLO | | 2-0 | Raluca Olaru / Sara Sorribes Tormo |  ROU |  ESP | | 6-3 | 6-2 | | 1:15 (64-43) |
| Wed 02.09.20 | Asia Muhammad / Taylor Townsend | USA | USA | | 2-1 | Bethanie Mattek-Sands / Shuai Zhang | USA | CHN | 5 | 3-6 | 6-2 | 6-1 | 1:42 (82-70) |
| Thu 03.09.20 | Nicole Melichar / Yifan Xu | USA | CHN | 3 | 2-0 | Kirsten Flipkens / Alison Van Uytvanck | BEL | BEL | | 6-4 | 7-64 | | 1:36 (82-67) |
| Wed 02.09.20 | Cori Gauff / Caty Mcnally | USA | USA | | 2-0 | Hailey Baptiste / Whitney Osuigwe | USA | USA | WC | 7-5 | 6-1 | | 1:16 (72-52) |
| Wed 02.09.20 | Hayley Carter / Luisa Stefani | USA | BRA | | 2-1 | Lyudmila Kichenok / Nadiya Kichenok |  UKR | UKR | | 6-4 | 5-7 | 6-3 | 2:01 (96-86) |
| Thu 03.09.20 | Shuko Aoyama / Ena Shibahara | JPN | USA | 6 | 2-0 | Ann Li / Bernarda Pera | USA | USA | WC | 6-4 | 7-5 | | 1:28 (76-65) |
| Thu 03.09.20 | Anna-Lena Friedsam / Katerina Siniakova | GER | CZE | 8 | 2-0 | Usue Maitane Arconada / Christina McHale | USA | USA | WC | 6-4 | 6-3 | | 1:21 (71-56) |
| Wed 02.09.20 | Anna Blinkova / Veronika Kudermetova | RUS | RUS | | 2-1 | Nao Hibino / Makoto Ninomiya | JPN | JPN | | 6-4 | 5-7 | 6-4 | 1:58 (103-91) |
| Thu 03.09.20 | Oksana Kalashnikova / Alla Kudryavtseva | GEO | RUS | | 2-1 | Jennifer Brady / Caroline Dolehide | USA | USA | | 2-6 | 6-4 | 7-5 | 1:50 (99-93) |
| Thu 03.09.20 | Kveta Peschke / Demi Schuurs | CZE | NED | 4 | 2-0 | Sharon Fichman / Darija Jurak | CAN |  CRO | | 6-2 | 7-66 | | 1:33 (73-68) |
| Wed 02.09.20 | Victoria Azarenka / Sofia Kenin | BLR | USA | 7 | 2-1 | Ellen Perez / Storm Sanders |  AUS | AUS | | 2-6 | 6-2 | 6-2 | 1:36 (86-73) |
| Wed 02.09.20 | Laura Siegemund / Vera Zvonareva | GER | RUS | | 2-0 | Alexa Guarachi / Desirae Krawczyk | USA | USA | | 6-3 | 6-0 | | 1:01 (57-35) |
| Thu 03.09.20 | Jessica Pegula / Shelby Rogers | USA | USA | WC | 2-0 | Viktoria Kuzmova / Aliaksandra Sasnovich |  SVK | BLR | | 6-1 | 6-4 | | 1:07 (64-42) |
| Wed 02.09.20 | Elise Mertens / Aryna Sabalenka | BEL | BLR | 2 | 2-0 | Anastasia Rodionova / Sabrina Santamaria |  AUT | USA | | 6-2 | 6-0 | | 0:51 (59-31) |
